第十四章 紅外分光光度法
紅外線:infrared ray,IR
中紅外吸收光譜:mid-infrared absorption spectrum,Mid-IR
遠紅外光譜:Far-IR
微波譜:microwave spectrum,MV
紅外吸收光譜法:infrared spectroscopy
紅外分光光度法:infrared spectrophotometry
振動形式:mode of vibration
伸縮振動:stretching vibration
對稱伸縮振動:symmetrical stretching vibration
不對稱伸縮振動:asymmetrical stretching vibration
彎曲振動:bending vibration
變形振動:formation vibration
面內彎曲振動:in-plane bending vibration,β
剪式振動:scissoring vibration,δ
面內搖擺振動:rocking vibration,ρ
面外彎曲振動:out-of-plane bending vibration,γ
面外搖擺振動:wagging vibration,ω
蜷曲振動:twisting vibration ,τ
對稱變形振動:symmetrical deformation vibration ,δs
不對稱變形振動:asymmetrical deformation vibration, δas
特征吸收峰:charateristic avsorption band
特征頻率:characteristic frequency
相關吸收峰:correlation absorption band
雜化影響:hybridization affect
環大小效應:ring size effect
吸收峰的強度:intensity of absorption band
環折疊振動:ring prckering vibration
第十五章 原子吸收分光光度法
原子光譜法:atomic spectroscopy
原子吸收分光光度法:atomic absorption spectrophotometry,AAS
原子發射分光光度法:atomic emmsion spectrophotometry,AES
原子熒光分光光度法:atomic fluorescence spectrophotometry,AFS
第十六章 核磁共振波譜法
核磁共振:nuclear magnetic resonance,NMR
核磁共振波譜:NMR spectrum
核磁共振波譜法:NMR spectroscopy
掃場:swept field
掃頻:seept frequency
連續波核磁共振:continuous wave NMR,CW NMR
Fourier變換NMR:PFT-NMR,FT-NMR
二維核磁共振譜:2D-NMR
質子核磁共振譜:proton magnetic resonance spectrum,PMR
氫譜:1H-NMR
碳-13核磁共振譜:13C-NMR spectrum,13CNMR
自旋角動量:spin angular momentum
磁旋比:magnetogyric ratio
磁量子數:magnetic quantum number,m
進動:precession
弛豫歷程:relaxation mechanism
局部抗磁屏蔽:local diamagnetic shielding
屏蔽常數:shielding constant
化學位移:chemical shift
國際純粹與應用化學協會:IUPAC
磁各向異性:magnetic anisotropy
遠程屏蔽效應:long range shielding effect
結面:nodal plane
自旋-自旋偶合:spin-spin coupling
自旋-自旋分裂:spin=spin splitting
單峰:singlet,s
雙峰:doublet,d
三重峰:triplet,t
四重峰:quartet
五重峰:quintet
六重峰:sextet
偕偶:geminal coupling
鄰偶:vicinal coupling
遠程偶合:long range coupling
磁等價:magnetic eqivalence
自旋系統:spin system
一級光譜:first order spectrum
二級光譜(二級圖譜):second order spectrum
C-H光譜:C-H correlated spectroscopy,C-H COSY
第十七章 質譜法
質譜分析法:mass spectrometry
質譜:mass spectrum,MS
棒圖:bar graph
選擇離子檢測:selected ion monitoring ,SIM
直接進樣:direct probe inlet ,DPI
接口:interface
氣相色譜-質譜聯用:gas chromatography-mass spectrometry,GC-MS
高效液相色譜-質譜聯用:high performance liquid chromatography-mass spectrometry,HPLC-MS
電子轟擊離子源:electron impact source,EI
離子峰:quasi-molecular ions
化學離子源:chemical ionization source,CI
場電離:field ionization,FI
場解析:field desorptiion,FD
快速原子轟擊離子源:fast stom bombardment ,FAB
質量分析器:mass analyzer
磁質譜儀:magnetic-sector mass spectrometer
四極桿質譜儀(四極質譜儀):quadrupole mass spectrometer
原子質量單位:amu
離子豐度:ion abundance
相對豐度(相對強度):relative avundance
基峰:base peak
質量范圍:mass range
分辨率:resolution
靈敏度:sensitivity
信噪比:S/N
分子離子:molecular ion
碎片離子:fragment ion
同位素離子:isotopic ion
亞穩離子:metastable ion
亞穩峰:metastable peak
母離子:paren ion
子離子:daughter
含奇數個電子的離子:odd electron
含偶數個電子的離子:even eletron,EE
均裂:homolytic cleavage
異裂(非均裂):heterolytic cleavage
半均裂:hemi-homolysis cleavage
重排:rearragement
分子量:MW
α-裂解:α-cleavage
第十八章 色譜分析法概論
色譜法(層析法):chromatography
固定相:stationary phase
流動相:mobile phase
超臨界流體色譜法:SFC
高效毛細管電泳法:high performance capillary electroporesis,HPEC
氣相色譜法:gas chromatography,GC
液相色譜法:liquid cromatography,LC
超臨界流體色譜法:supercritical fluid chromatography,SFC
氣-固色譜法:GSC
氣-液色譜法:GLC
液-固色譜法:LSC
液-液色譜法:LLC
柱色譜法:column chromatography
填充柱:packed column
毛細管柱:capillary column
微填充柱:icrobore packed column
高效液相色譜法:high performance liquid chromatography,HPLC
平板色譜法:planar
平板色譜法:plane chromatography
紙色譜法:paper chromatography
薄層色譜法:thin layer chromatography,TLC
薄膜色譜法;thiin film chomatography
毛細管電泳法:capillary electrophoresis,CE
分配色譜法:partition chromatography
吸附色譜法:adsorpion chromaography
離子交換色譜法:ion exchange chromatography,IEC
空間排阻色譜法:steric exclusion chromatography,SEC
親和色譜法:affinity chromatography
分配系數:distribution cofficient
狹義分配系數:partition coefficient
凝膠色譜法:gel chromatography
凝膠滲透色譜法:gel permeation chromatography,GPC
凝膠過濾色譜法:gel filtration chromatography,GFC
滲透系數:permeation coefficien;Kp
化學鍵合相色譜法:chemically bonded-phase chromatography
分配系數:distribution coefficient
靛菁綠:indocyanine
氣相色譜-傅立葉變換紅外光譜:GC-FTIR
第十九章 經典液相色譜法
薄層色譜法:TLC
吸附:adsorption
活化:activation
脫活性:deactivation
交聯度:degree of cross linking
交換容量:exchange capacity
薄層板:thin layer plate
展開劑:developing solvent ,developer
臨界膠束濃度:criticak micolle concentration ,CMC
相對比移值:relative Rf, Rr
分離度:resolution ,R
分離數:separation number,SN
煅石膏:Gypsum
羧甲基纖維素鈉:CMC-Na
吸收光譜聯用:TLC-UV
薄層色譜-熒光聯用:TLC-F
薄層色譜-紅外吸收光譜聯用:TLC-IR
薄層色譜法:TLC-MS
紙色譜法:paper chromatography
上行展開:ascending development
下行法展開:descending development
雙向展開:two dimensional develoooment
第二十章 氣相色譜法
氣相色譜法:gas chromatography
前延峰:leading peak
拖尾峰:tailing peak
對稱因子:symmetry factor,fs
保留時間:retention time
保留體積:retention volume
死時間:dead time
調整保留時間:asjusted retention time
半峰寬:peak width at half height,W1/2 or Y1/2
峰寬:peak width,W
等溫線:isotherm
理論塔板高度:height equivalent to atheoretical plate
化學鍵合相:chemically bonded phase
丁二酸二乙二醇聚酯:polydiethylene glycol succinate,PDEGS,DEGS
高分子多孔微球:GDX
苯乙烯:STY
乙基乙烯苯:EST
二乙烯苯:DVB
涂壁毛細管柱:wall coated open tubular column,WCOT
載體涂層毛細管柱:supprot coated open tubular column,SCOT
熱導檢測器:thermal conductivity detector,TCD
氫焰離子化檢測器:hydrogen flame ionization detector,FID
電子捕獲檢測器:electron capture detector ,ECD
噪聲:noise,N
漂移:drift,d
靈敏度:sensitivity
檢測限(敏感度):detectability,D,M
分離度:resolution
歸一化法:normalization method
外標法:external standardization
第二十一章 高效液相色譜法
高效液相色譜法:high performance liquid chromatography,HPLC
高速液相色譜法:high speed LC,HSLC
高壓液相色譜法:high pressure LC,HPLC
高分辨液相色譜法:high resolution LC,HRLC
液固吸附色譜法(液固色譜法):liquid-solid adsorption chromatography,LSC
液液色譜法:liquid-liquid chromatography,LLC
正相:normal phase,NP
反相:reversed phase,RP
化學鍵合相色譜法:bonded phase chromatography,BPC
十八烷基:octadecylselyl,ODS
離子對色譜法:paired ion chromatography,PIC
反相離子對色譜法:RPIC
離子抑制色譜法:ion suppression chromatography,ISC
離子色譜法:ion chromatography,IC
手性色譜法:chiral chromatography,CC
環糊精色譜法:cyclodextrin chromatography,CDC
膠束色譜法:micellar chromatography,MC
親和色譜法:affinity chromatography,AC
固定相:stationary phase
化學鍵合相:chemically bonde phase
封尾、封頂、遮蓋:end capping
手性固定相:chiral stationary phase,CSP
恒組成溶劑洗脫:isocraic elution
梯度洗脫:gradient elution
紫外檢測器:ultraviolet detector,UVD
熒光檢測器:fluorophotomeric detector,FD
電化學檢測器:ECD
示差折光檢測器:RID
光電二極管檢測器:photodiode array detector ,DAD
三維光譜-波譜圖:3D-spectrochromatogram
蒸發光散射檢測器:evaporative light scattering detector,ELSD
安培檢測器:ampere detector,AD
高效毛細管電泳法:high performance capillary electrophoresis,HPCE
淌度:mobility
電泳:electrophoresis
電滲:electroosmosis
動力進樣:hydrodynamic injection
電動進樣:electrokinetic injection
毛細管區帶電泳法:capillary zone electrophoresis,CZE
膠束電動毛細管色譜:micellar electrokinetic capillary chromatography,MECC
毛細管凝膠電泳:capillary gel electrophoresis,CGE
篩分:sieving